Could not download image of conceptual_captions?

[heyichang]

headers = {
#'User-Agent': 'Mozilla/5.0 (X11; Linux x86_64) AppleWebKit/537.36 (KHTML, like Gecko) Chrome/71.0.3578.98 Safari/537.36',
'User-Agent':'Googlebot-Image/1.0', # Pretend to be googlebot
'X-Forwarded-For': '64.18.15.200'
}

try this url 'https://i.pinimg.com/736x/94/8e/5e/948e5e26c5e79a6b7db24accf918e98f--jean-skirts-cowboy-boots.jpg'

response = requests.get('https://i.pinimg.com/736x/94/8e/5e/948e5e26c5e79a6b7db24accf918e98f--jean-skirts-cowboy-boots.jpg', stream=False, timeout=10, allow_redirects=True, headers=headers)

get the error
ConnectTimeoutError